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Creators/Authors contains: "Bhuvanesh, Nattamai"

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  1. ; ; ; (, Polyhedron)
    Free, publicly-accessible full text available November 1, 2025
  2. ; ; ; (, Polyhedron)
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  3. ; ; ; ; (, Journal of Organometallic Chemistry)
    In a seminal 1972 study, TESCxTES with x = 8, 12, 16, and 24 (TES = SiEt3) were presented as unisolable and thus only characterized by UV-visible spectroscopy. We find that TESC24TES is obtained from the reaction of trans-(C6F5)(p-tol3P)2Pt(C≡C)5SiEt3 and crude HC8TES under Hay oxidative cross coupling conditions. Hay oxidative homocouplings of HC4TES and crude HC8TES afford TESC8TES (83%) and TESC16TES (5%). A Cadiot-Chodkiewicz reaction of BrC4Br and HC4TES (2 equiv) yields TESC12TES (11%). All of these compounds are crystalline, and the crystal structures of TESC8TES and TESC16TES are determined. 
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  4. ; ; ; ; ; ; ; (, Chemical Communications)
    A rare cuprous triangle featuring a reactive organocopper site is captured by a new flexible bis(amidinate) ligand from the oligomeric mesitylcopper framework and interconverts with another equivalent of ligand into a tetracuprous Möbius strip. 
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  5. ; ; ; ; (, Dalton Transactions)
    A bimetallic Pd complex of a bis(pincer) with a diarylpyrazine core has been prepared. 
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  6. ; ; (, Inorganic Chemistry)
  7. ; ; (, Organometallics)
  8. ; ; ; ; (, Journal of Organometallic Chemistry)
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  9. ; ; (, Dalton Transactions)
    CuI catalyzes reactions of cis -(R 2 C(CH 2 PPh 2 ) 2 )Pt(CCCCH) 2 and cis -(R 2 C(CH 2 PPh 2 ) 2 )PtI 2 in secondary amine solvents HNR’ 2 to give the title adducts [(R 2 C(CH 2 PPh 2 ) 2 )Pt(CCCC)] 4 ·(H 2 NR’ 2 + I − ) n (R/R’/ n = Me/Et/1, Me/((CH 2 CH 2 ) 2 O) 0.5 /3, Et/Et/1, Et/CH 2 CHCH 2 /1; 92–42%). Crystal structures of these or closely related species establish folded Pt 4 cores containing ammonium cation guests, with NH/ and NCH/CC hydrogen bonding. DOSY NMR experiments show that the host/guest relationship can be maintained in solution. 
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  10. ; ; ; (, European Journal of Inorganic Chemistry)
    Abstract Reactions oftrans‐(C6F5)(p‐tol3P)2Pt(C≡C)nSiEt3(PtC2nSi;n=5, 7, 9) and excessPtClin the presence of wetn‐Bu4N+F−(to effect protodesilylation) under Sonogashira‐type conditions (CuCl, base, other additives) afford the title compoundsPtC10Pt,PtC14Pt, andPtC18Ptin 42–32 % yields. A four‐fold substitution of the phosphine ligands inPtC10Ptby PEt3affordsPt'C10Pt’(78 %), and a Sonogashira reaction ofPt'C2HandPt'ClaffordsPt'C2Pt’(68 %). The analogous reaction withPtC2SiandPtClis unsuccessful, presumably for steric reasons. The crystal structures ofPtC10Pt,PtC14Pt,Pt'C10Pt′, andPt'C2Pt’exhibit a number of interesting trends and features. Certain sp chain extension reactions that lead to or employ the precursorsPtC10Si,PtC12Si,PtC14Si, andPtC18Sisometimes give byproducts derived from C2loss, and possible origins are discussed. Related phenomena have been reported by others in the course of synthesizing extended conjugated polyynes. 
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